Interactions between halide anions and interfacial water molecules in relation to the Jones-Ray effect.
نویسندگان
چکیده
The Jones-Ray effect is shown to be governed by a different mechanism to enhanced anion adsorption. Halide ions at sub-molar concentrations are not exposed to the vapour phase; instead their first-solvating shell intimately interacts with the outmost water layer. Our novel proposal opens challenges for predicting related interfacial phenomena consistently.
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ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 16 45 شماره
صفحات -
تاریخ انتشار 2014